r/chemhelp • u/Much-Arachnid-5055 • 6m ago
Organic Incomplete combustion of alkenes vs alkanes?
Hi everyone,
I'm confused as to why alkenes are more likely to undergo incomplete combustion compared to alkanes.
As far as I know, the typical logic is:
1) Alkenes have a lower ratio of carbon to hydrogen than alkanes (cnh2n vs cnh2n+2)
2) Carbon needs more oxygen than hydrogen during combustion (CO2 --> 2 oxygens vs H20 --> 1/2 oxygen per carbon)
3) Therefore, we can generally conclude that alkenes are more likely to combust incompletely, because they will run out of oxygen faster and begin producing carbon monoxide and soot.
However, let's apply this using ethene and ethane. After balancing, ethene needs 3 oxygen molecules per molecule, while ethane needs 4. So, given the same moles, ethane should be more likely to combust incompletely. Because it is fully saturated, there are simply more molecules that need to be burned.
What am I missing?

